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Ionic Radius Ionic Radius



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Ionic Radius

Ionic Radius

  • How do I remember this?????
  • The more electrons that are lost, the greater the reduction in size.
  • Li+1 Be+2
  • protons 3 protons 4
  • electrons 2 electrons 2
  • Which ion is smaller?

Ionic Radius

  • How do I remember this???
  • The more electrons that are gained, the greater the increase in size.
  • P-3 S-2
  • protons 15 protons 16
  • electrons 18 electrons 18
  • Which ion is smaller?

Ionization Energy

  • Ionization Energy – energy needed to remove outermost e-

Ionization Energy

  • Group Trend – As you go down a column, ionization energy decreases
  • As you go down, atomic size is increasing (less attraction), so easier to remove an e-
  • Periodic Trend – As you go across a period (L to R), ionization energy increases
  • As you go L to R, atomic size is decreasing (more attraction), so more difficult to remove an e-
  • (also, metals want to lose e-, but nonmetals do not)

Electronegativity

  • Electronegativity- tendency of an atom to attract e-

Electronegativity Trend

  • Group Trend – As you go down a column, electronegativity decreases
  • As you go down, atomic size is increasing, so less attraction to its own e- and other atom’s e-
  • Periodic Trend – As you go across a period (L to R), electronegativity increases
  • As you go L to R, atomic size is decreasing, so there is more attraction to its own e- and other atom’s e-

Oxides

  • Generally can be prepared by direct combination of
  • elements with oxygen
  • spontaneous
  • slowly at room temperature
  • occurs on heating
  • high temperature
  • e.g. alkali metals
  • e.g. magnesium
  • e.g. carbon
  • e.g. nitrogen
  • Oxidation number of the oxides
  •  1) The oxidation number of elements in its oxides corresponds to the number of electrons used for bonding.
  •  2) The maximum oxidation number is the same as the group number of the element. It also corresponds to the total number of outermost electrons used for bonding.
  • 3) Oxidation numbers of elements for their oxides are always positive as
  • - oxygen are more electronegative than any of the third period elements.
  • 4) P and S show several oxidation numbers as
  • - has energetically available 3d subshells
  • - for expansion of octet to accommodate more than 8 electrons.


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