complicated. A major contributor to air pollution in Southern California
56
was the exhaust from cars and trucks, a fact vehemently denied by the
automobile industry until it was irrefutably proven by Arie Haagen-Smit at
the California Institute of Technology in the early 1950s. Today, cars and
light trucks account for about 60 percent of smog-creating emissions in
the region, so any successful effort to reduce air pollution has to take full
account of the emissions produced by the region‟s large vehicle
population.
Motor vehicle emissions are converted to smog through a series of
chemical reactions that occur in the presence of sunlight. Uncontrolled
vehicles produce the constituents of smog in a number of ways: through
the venting of vaporized gasoline, the emission of gases from the
engine‟s crankcase, and most important through the combustion process
that converts gasoline into the power that propels them. When a charge
of air and vaporized fuel is compressed and then ignited in an engine‟s
combustion chamber, not all of the fuel is completely combusted; some
unburned hydrocarbons are emitted. At the same time, high
temperatures and pressures within the combustion chamber convert
atmospheric nitrogen into various oxides of nitrogen (NO
x
for short). The
exhaust gases are then released into the atmosphere, where the
ultraviolet portion of sunlight breaks down NO
2
, one of the oxides of
nitrogen, into NO. The liberated oxygen atoms then combine with
atmospheric oxygen (O
2
) to produce one of the major constituents of
photochemical smog: ozone (O
3
), a major irritant to the respiratory
system. At the same time, other oxides of nitrogen are converted into a
variety of compounds, notably the peroxyacyl nitrates that contribute to
the eye-burning effects of smog. Residual NO
2
adds to the general
nastiness by obscuring vision with a brown haze.
Combustion of gasoline in an engine also produces carbon monoxide
(CO), carbon dioxide (CO
2
), water vapor, sulfur dioxide, and particulates.
57
Strictly speaking, these are not constituents of photochemical smog.
They are still a significant problem, however. Recent years have been a
growing concern about the emission of CO
2
into the atmosphere
because it may contribute to a “greenhouse effect” and consequent
global warming. Solid proof of this phenomenon remains elusive, but the
increasing likelihood that today‟s car and trucks are contributing to global
warming may necessitate the eventual supplantation of fossil-fuel
burning internal-combustion engines by other sources of power; no
matter how clean it is in other respects, an internal-combustion engine
powered by a carbon-based fuel will always produce CO
2
.
From ―Inventing for the Environment‖
(2003),
edited by Arthur Molella and Joyce Bedi.
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